Fractional distillation and petrochemicals (4.7.1.2) — AQA GCSE Chemistry Revision Notes

Revision notes for AQA GCSE Chemistry specification point 4.7.1.2, Fractional distillation and petrochemicals.

FRACTIONAL DISTILLATION OF CRUDE OIL

FRACTIONAL DISTILLATION is the method used to separate the MIXTURE OF HYDROCARBONS in crude oil.

 The process includes:

HEATING AND VAPORISATION

  • Crude oil is HEATED until most hydrocarbons turn into GAS.
  • These gases enter a FRACTIONATING COLUMN where there's a TEMPERATURE GRADIENT (hot at the bottom, cooler as you go up).

 

SEPARATION BY BOILING POINTS

  • LONGER HYDROCARBONS with HIGHER boiling points CONDENSE back into liquids at the LOWER part of the column.
  • SHORTER HYDROCARBONS with LOWER boiling points travel further up and condense at higher levels.

 Fractional Distillation

  • The different hydrocarbon fractions are collected at various levels, each with a similar boiling points and HYDROCARBON LENGTH.

 

PRODUCTS FROM DISTILLATION

  • The FRACTIONS produced from the fractional distillation include LPG, Petrol, Kerosene, Diesel, Heavy Fuel Oil and Bitumen.
  • The fractions can then be processed to produce fuels and feedstock for the PETROCHEMICAL INDUSTRY.
  • Many useful materials on which modern life depends on are produced by the petrochemical industry, such as SOLVENTS, LUBRICANTS, POLYMERS and DETERGENTS.


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